1,4-Diazo-niabicyclo-[2.2.2]octane bis-(2-chloro-benzoate)
Research output: Contribution to journal › Journal article › Research › peer-review
The title compound, C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (-), contains trimeric units linked by N-H⋯O hydrogen bonds. The carboxyl-ate groups of the 2-chloro-benzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chloro-benzene rings to which they are bound. The hydrogen-bonded trimers are arranged in layers in the (200) planes and the chloro-benzoate anions form edge-to-face inter-actions between layers, with dihedral angles of 61.9 (1) and 49.8 (1)° and centroid-centroid distances of 4.85 (1) and 4.65 (1) Å, respectively, for two crystallographically distinct inter-actions.
Original language | English |
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Journal | Acta Crystallographica. Section E: Structure Reports Online |
Volume | 64 |
Issue number | Pt 8 |
Pages (from-to) | o1416 |
ISSN | 1600-5368 |
DOIs | |
Publication status | Published - 2008 |
Externally published | Yes |
ID: 46275457