1,4-Diazo-niabicyclo-[2.2.2]octane bis-(2-chloro-benzoate)

Research output: Contribution to journal › Journal article › Research › peer-review

Standard

1,4-Diazo-niabicyclo-[2.2.2]octane bis-(2-chloro-benzoate). / Skovsgaard, Signe; Bond, Andrew D.

In: Acta Crystallographica. Section E: Structure Reports Online, Vol. 64, No. Pt 8, 2008, p. o1416.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Skovsgaard, S & Bond, AD 2008, '1,4-Diazo-niabicyclo-[2.2.2]octane bis-(2-chloro-benzoate)', Acta Crystallographica. Section E: Structure Reports Online, vol. 64, no. Pt 8, pp. o1416. https://doi.org/10.1107/S1600536808020096

APA

Skovsgaard, S., & Bond, A. D. (2008). 1,4-Diazo-niabicyclo-[2.2.2]octane bis-(2-chloro-benzoate). Acta Crystallographica. Section E: Structure Reports Online, 64(Pt 8), o1416. https://doi.org/10.1107/S1600536808020096

Vancouver

Skovsgaard S, Bond AD. 1,4-Diazo-niabicyclo-[2.2.2]octane bis-(2-chloro-benzoate). Acta Crystallographica. Section E: Structure Reports Online. 2008;64(Pt 8):o1416. https://doi.org/10.1107/S1600536808020096

Author

Skovsgaard, Signe ; Bond, Andrew D. / 1,4-Diazo-niabicyclo-[2.2.2]octane bis-(2-chloro-benzoate). In: Acta Crystallographica. Section E: Structure Reports Online. 2008 ; Vol. 64, No. Pt 8. pp. o1416.

Bibtex

@article{a4a9ddc0d51546f2ada455c027bc18e9,
title = "1,4-Diazo-niabicyclo-[2.2.2]octane bis-(2-chloro-benzoate)",
abstract = "The title compound, C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (-), contains trimeric units linked by N-H⋯O hydrogen bonds. The carboxyl-ate groups of the 2-chloro-benzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chloro-benzene rings to which they are bound. The hydrogen-bonded trimers are arranged in layers in the (200) planes and the chloro-benzoate anions form edge-to-face inter-actions between layers, with dihedral angles of 61.9 (1) and 49.8 (1)° and centroid-centroid distances of 4.85 (1) and 4.65 (1) {\AA}, respectively, for two crystallographically distinct inter-actions.",
author = "Signe Skovsgaard and Bond, {Andrew D}",
year = "2008",
doi = "10.1107/S1600536808020096",
language = "English",
volume = "64",
pages = "o1416",
journal = "Acta Crystallographica Section E: Crystallographic Communications",
issn = "1600-5368",
publisher = "Wiley-Blackwell",
number = "Pt 8",

}

RIS

TY - JOUR

T1 - 1,4-Diazo-niabicyclo-[2.2.2]octane bis-(2-chloro-benzoate)

AU - Skovsgaard, Signe

AU - Bond, Andrew D

PY - 2008

Y1 - 2008

N2 - The title compound, C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (-), contains trimeric units linked by N-H⋯O hydrogen bonds. The carboxyl-ate groups of the 2-chloro-benzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chloro-benzene rings to which they are bound. The hydrogen-bonded trimers are arranged in layers in the (200) planes and the chloro-benzoate anions form edge-to-face inter-actions between layers, with dihedral angles of 61.9 (1) and 49.8 (1)° and centroid-centroid distances of 4.85 (1) and 4.65 (1) Å, respectively, for two crystallographically distinct inter-actions.

AB - The title compound, C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (-), contains trimeric units linked by N-H⋯O hydrogen bonds. The carboxyl-ate groups of the 2-chloro-benzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chloro-benzene rings to which they are bound. The hydrogen-bonded trimers are arranged in layers in the (200) planes and the chloro-benzoate anions form edge-to-face inter-actions between layers, with dihedral angles of 61.9 (1) and 49.8 (1)° and centroid-centroid distances of 4.85 (1) and 4.65 (1) Å, respectively, for two crystallographically distinct inter-actions.

U2 - 10.1107/S1600536808020096

DO - 10.1107/S1600536808020096

M3 - Journal article

C2 - 21203135

VL - 64

SP - o1416

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

SN - 1600-5368

IS - Pt 8

ER -

ID: 46275457