Squeezing the [Cu-OH...H2O-Cu]3+ bridge by cryptate encapsulation

Research output: Contribution to journal › Journal article › Research › peer-review

Standard

Squeezing the [Cu-OH...H2O-Cu]3+ bridge by cryptate encapsulation. / Bond, Andrew D; Derossi, Sofia; Jensen, Frank; Larsen, Frank B; McKenzie, Christine; Nelson, Jane.

In: Inorganic Chemistry, Vol. 44, No. 17, 22.08.2005, p. 5987-9.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Bond, AD, Derossi, S, Jensen, F, Larsen, FB, McKenzie, C & Nelson, J 2005, 'Squeezing the [Cu-OH...H2O-Cu]3+ bridge by cryptate encapsulation', Inorganic Chemistry, vol. 44, no. 17, pp. 5987-9. https://doi.org/10.1021/ic0505091

APA

Bond, A. D., Derossi, S., Jensen, F., Larsen, F. B., McKenzie, C., & Nelson, J. (2005). Squeezing the [Cu-OH...H2O-Cu]3+ bridge by cryptate encapsulation. Inorganic Chemistry, 44(17), 5987-9. https://doi.org/10.1021/ic0505091

Vancouver

Bond AD, Derossi S, Jensen F, Larsen FB, McKenzie C, Nelson J. Squeezing the [Cu-OH...H2O-Cu]3+ bridge by cryptate encapsulation. Inorganic Chemistry. 2005 Aug 22;44(17):5987-9. https://doi.org/10.1021/ic0505091

Author

Bond, Andrew D ; Derossi, Sofia ; Jensen, Frank ; Larsen, Frank B ; McKenzie, Christine ; Nelson, Jane. / Squeezing the [Cu-OH...H2O-Cu]3+ bridge by cryptate encapsulation. In: Inorganic Chemistry. 2005 ; Vol. 44, No. 17. pp. 5987-9.

Bibtex

@article{aa0fbbf83ecb4a14904d671ffc7f8269,
title = "Squeezing the [Cu-OH...H2O-Cu]3+ bridge by cryptate encapsulation",
abstract = "Treatment of cryptand L(1) with Cu(II) generates a H3O2(-)-bridged dicopper(II) cryptate, 2, where the guest anion has responded to steric constraint by a significant shortening of the O-O distance to 2.325(9) A; computational optimization at the B3LYP/6-31(d) level suggests that the bridging O-H...O H-bond is bent (approximately 157 degrees) but that the barrier to interchange of the bridging H atom is low (",
author = "Bond, {Andrew D} and Sofia Derossi and Frank Jensen and Larsen, {Frank B} and Christine McKenzie and Jane Nelson",
year = "2005",
month = aug,
day = "22",
doi = "10.1021/ic0505091",
language = "English",
volume = "44",
pages = "5987--9",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "17",

}

RIS

TY - JOUR

T1 - Squeezing the [Cu-OH...H2O-Cu]3+ bridge by cryptate encapsulation

AU - Bond, Andrew D

AU - Derossi, Sofia

AU - Jensen, Frank

AU - Larsen, Frank B

AU - McKenzie, Christine

AU - Nelson, Jane

PY - 2005/8/22

Y1 - 2005/8/22

N2 - Treatment of cryptand L(1) with Cu(II) generates a H3O2(-)-bridged dicopper(II) cryptate, 2, where the guest anion has responded to steric constraint by a significant shortening of the O-O distance to 2.325(9) A; computational optimization at the B3LYP/6-31(d) level suggests that the bridging O-H...O H-bond is bent (approximately 157 degrees) but that the barrier to interchange of the bridging H atom is low (

AB - Treatment of cryptand L(1) with Cu(II) generates a H3O2(-)-bridged dicopper(II) cryptate, 2, where the guest anion has responded to steric constraint by a significant shortening of the O-O distance to 2.325(9) A; computational optimization at the B3LYP/6-31(d) level suggests that the bridging O-H...O H-bond is bent (approximately 157 degrees) but that the barrier to interchange of the bridging H atom is low (

U2 - 10.1021/ic0505091

DO - 10.1021/ic0505091

M3 - Journal article

C2 - 16097817

VL - 44

SP - 5987

EP - 5989

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 17

ER -

ID: 46282938