A multiscale study of hot-extruded CoNiGa ferromagnetic shape-memory alloys

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Documents

  • Stavros Samothrakitis
  • Camilla Buhl Larsen
  • Robin Woracek
  • Ludek Heller
  • Jaromir Kopecek
  • Gregory Gerstein
  • Hans Juergen Maier
  • Michal Rames
  • Michael Tovar
  • Petr Sittner
  • Soren Schmidt
  • Markus Strobl

Ferromagnetic shape-memory CoNiGa alloys have attracted much scientific interest due to their potential alternative use as high-temperature shape-memory alloys, bearing a high prospect for actuation and damping applications at elevated temperatures. Yet, polycrystalline CoNiGa, due to strong orientation dependence of transformation strains, suffers from intergranular fracture. Here, two multi-grain CoNiGa samples were prepared by a novel hot extrusion process that can promote favourable grain-boundary orientation distribution and improve the material's mechanical behaviour. The samples were investigated by multiple methods and their micro structural, magnetic, and mechanical properties are reported. It is found that a post-extrusion solutionising heat treatment leads to the formation of a two-phase oligocrystalline homogeneous microstructure consisting of an austenitic parent B2 phase and gamma-CoNiGa precipitates. Reconstruction of the full 3D grain morphology revealed large, nearly spherical grains with no low-angle grain boundaries throughout the entire sample volume. The presence of gamma precipitation affects the transformation behaviour of the samples, by lowering the martensitic transformation temperature, while, in conjunction with the oligocrystalline microstructure, it improves the ductility. Controlling the composition of the B2 matrix, as well as the phase fraction of the gamma phase, is thus crucial for the optimal behaviour of the alloys. (c) 2020 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http:// creativecommons.org/licenses/by-nc-nd/4.0/).

Original languageEnglish
Article number109118
JournalMaterials and Design
Volume196
Number of pages10
ISSN0264-1275
DOIs
Publication statusPublished - Nov 2020

    Research areas

  • Martensitic transformation, Hot-extrusion, Laue three-dimensional neutron diffraction to-mography, Co-Ni-Ga, Ferromagnetic shape-memory alloy, CO-NI-GA, MARTENSITIC-TRANSFORMATION, COMPRESSION ASYMMETRY, PHASE-EQUILIBRIA, SINGLE-CRYSTALS, MAGNETIC-FIELD, MICROSTRUCTURE, PARTICLES, BEHAVIOR, TENSION

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